【視頻專訪】畢克助劑（上海）有限公司
9月2日-4日，2024中國國際復合材料工業技術展覽會在國家會展中心（上海）落下帷幕。展會上，畢克助劑（上海）有限公司大中華區塑料助劑業務總監范雷平先生接受了復材網的專訪，與我們分享了公司的發展歷程，介紹了本次參展的創新產品及下一步產品重點研發方向，同時表達了復合材料市場發展趨勢的看法。
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畢克化學
畢克化學是一家全球領的特種化學品供應商之一，公司的創新型助劑和差異化解決方案可優化產品和材料的特征以及生產和應用過程。畢克化學成立于1873，迄今有150年歷史。畢克化學的主要助劑產品包括潤濕分散劑，消泡劑，表面助劑，流變助劑和蠟助劑等；在復合材料領域，還提供專門針對玻璃纖維和碳纖維的偶聯劑和脫模劑等。
一直以來，畢克化學在可持續發展上不斷進取，推出了一系列先進產品，包括致力于氣候保護的BYK-ET系列、關注人類與環境健康的BYK-18系列、基于可再生原料的產品、旨在提升資源利用率和促進塑料回收的RECYCLOBYK系列。在功能性助劑方面，主要產品覆蓋纖維浸漬、碳基材料分散、偶聯劑、A級表面加工助劑以及無需打磨的內部脫模助劑等。
畢克化學的生產基地遍布全球，在德國的韋塞爾、肯彭、穆斯堡、施科堡和格雷茨里德，荷蘭的代芬特爾、代訥坎普和奈弗達爾，英國的韋德尼斯，美國的瓦林福德、切斯特、哥倫比亞、厄斯錫蒂、岡薩雷斯、路易斯維爾和匹茲福德以及中國的上海和銅陵都設有工廠。作為阿爾塔納集團旗下的子公司，畢克化學在全球擁有2,500名員。
新品展示
BYK-C 8001
全球首款經 Germanischer Lloyd（DNV GL） 認證的助劑
BYK-C 8001 顯著提高了材料的機械強度，使葉片更堅固，因此在幾乎相同重量下能制造更長的葉片。由于風力發電市場與航空市場一樣只使用經過認證的原材料，畢克化學決定申請 BYK-C 8001 作為全球第一款認證助劑。
表1 動態疲勞測試條件
表 2 動態疲勞測試數據
上表是“拉-拉”疲勞模式下最大循環次數的測試值。Control為對比測試樣?？梢钥闯?，低負載時，疲勞循環次數有明顯提升，最高達到5倍；在高負載下，疲勞循環次數也有25%-44%的提升。因此，偶聯劑對于復合材料的動態疲勞性能有正面的提升作用。
BYK-C 8001 可提升高達60%的機械性能，可優化葉片中纖維增強樹脂的機械強度和使用壽命。而且不用考慮玻纖的新舊，適用于每一種與環氧相容的玻纖，同時保持成品組件的一貫高質量。
BYK-W 907
特別適用于工程石（崗石）的潤濕分散劑
工程石板材的配方中填料含量很高，該材料必須通過壓實等方式成型。為了提高制品表面質量、降低空洞、干裂和微裂紋等不良效應，可以加入潤濕分散劑 BYK-W 907 ，該分散劑可以減少液相組份，降低原料成本，同時不影響最終產品的力學性能。
BYK-P 9912
具有內脫模功能的加工助劑，可實現風電拉擠大梁免打磨
在現有工藝條件下，去除脫模布而對大梁表面不做處理，會影響后續大梁板與灌注樹脂的界面粘接性能。BYK-P 9912 是一款具有內脫模功能的加工助劑，可實現制品免打磨直接灌注膠接，而且在界面性能的表現得到了拉擠企業的認可。
BYK-P 9912 是一款改性的超支化高分子聚合物，其中與樹脂不相容的低極性基團分布于樹脂與模具界面，實現制品的脫模功能。而與樹脂具有一定相容性的中極性分子主鏈和高極性基團能夠實現與樹脂更好的相容的同時，還能與樹脂之間產生化學鍵合力，在超支化物理錨固和化學鍵合力的雙重作用下, 能夠被牢固的鎖定在樹脂體系內而不二次遷移。
拉擠樣板
單搭剪切強度測試
BYK-P 9912 優勢：
BYK-1810 , BYK-1815
不含PFAS的有機硅消泡劑，用于溶劑型與無溶劑型體系
全氟烷基與多氟烷基物質（PFAS）在日常生活中被廣泛用于不粘涂層、消防泡沫或油漆等產品。但是，目前PFAS被懷疑可能對健康有害，因此其使用在全球范圍內都越來越受到限制。
這兩款全新的消泡劑具有高效出色的自發消泡性能，即使低用量也可實現自發消泡，完全不含氟，但是消泡效果與含PFAS產品相當。該系列助劑可用于各類溶劑型及無溶劑型體系，應用領域廣泛。
BYK-081
不含氟的透明性佳消泡劑
BYK-081 適用于溶劑型和胺中和、水可還原體系。該助劑取代了以前的 BYK-80 A，從而達到了即使不使用含氟組分也能很好地降低表面張力。由于其良好的相容性，BYK-081 可用于UP體系、環氧樹脂體系和聚氨酯體系，特別是透明應用。另外，也適用于國際認可的食品接觸應用。
優點：
不含氟
國際認可的食品接觸應用（根據美國食品藥品監督管理局 175.300、歐盟PIM（EC）10/201，中國 GB 9685-2008 等）
非常好的自發消泡效果
顯著降低表面張力，良好的基材潤濕性，無針孔
BYK-P 9920
提高玻纖/碳纖潤濕性能的加工助劑
BYK-P 9920 是一款兼具消泡和浸潤效果的綜合型助劑，在少量添加下，一方面能降低環氧樹脂和聚氨酯的粘度；另一方面能有效降低體系的表面張力，加快樹脂在纖維表面的鋪展，即：降低接觸角，從而進一步提升樹脂對纖維的浸潤，消除因潤濕不良而造成的制品干紗，氣孔等缺陷。
無助劑
添加BYK-P 9920
BYK-P 9920 在解決大絲束碳纖維拉擠大梁纖維浸潤問題上同樣具有顯著的效果。由于24K，48K，50K等大絲束碳纖維集束性很強，纖維直徑比玻纖小，在滿足合理的生產節奏下，很難在短時間內實現較好的絲束間，特別是絲束內的纖維浸潤。添加 BYK-P 9920 后，能夠非常明顯地解決大絲束碳纖維的浸潤問題，提高成品率，降低綜合成本，是碳纖維拉擠企業的首選助劑產品。
無助劑
添加 BYK-P 9920
BYK-P 9929
降低自由基固化體系放熱峰的加工助劑
不飽和聚酯和乙烯基酯樹脂的自由基聚合通常是一種明顯的放熱反應，釋放的能量會產生極高的溫度，溫度過高會導致聚合物翹曲、脆化、開裂甚至熱分解，因此，我們開發了一款加工助劑，在不降低其他性能的情況下降低放熱峰。
由于溫度過高而開裂
1）在乙烯基樹脂體系的效果
添加1% BYK-P 9929 ，放熱峰從176°C降低到133°C。固化時間的延遲可以通過補加0.2%的鈷促進劑消除影響，而且不會使放熱峰升高。
2）在鄰苯不飽和聚酯中的效果
BYK-P 9929 可降低鈷促進樹脂體系使用不同過氧化物固化劑的放熱峰。
3）在胺促進BPO固化體系的效果
BYK-P 9929 降低了胺促進體系原子灰樹脂的放熱峰。
除了可以降低系統的放熱峰外，BYK-P 9929 還有眾多優異性能，包括對力學性能影響很小，對產品固化沒有影響，液體易于混合，在樹脂中貯存穩定等。
RHEOBYK-410
中等極性液體流變添加劑
適用于溶劑型無溶劑涂料體系以及PVC塑料溶膠和室溫固化樹脂系統，還適用于紫外線固化系統，如CIPP, 助劑產生很高的觸變性性，從而改善抗流掛性和抗沉降性能?？梢赃M行后期添加
對于 CIPP 應用
與固體流變劑相比，提高了紫外光固化的效率
取代傳統增稠產品，可恢復的增稠行為，CIPP 在固化前的保質期比 MgO 增稠系統更長
據范雷平先生介紹，高性能先進復合材料領域的發展主要集中在碳纖維復合材料的應用，輕量化，長使用壽命等方面。綠色，可循環使用的復材主要在可回收，比如熱塑型復材，可降解材料包括生物降解，化學降解。這都將是復材重點關注的方向。除此之外，低毒無毒溶劑乃至無溶劑的樹脂及預浸料產品，采用低能耗及低廢棄物產生量的復合材料也是重點關注的方面。
聯系方式
畢克助劑（上海）有限公司
電話：+86-21-3749 8888
傳真：+86-21-3749 8899
地址：上海化學工業區普工路25號
